fac-Tricarbonyl Rhenium(I) Azadipyrromethene Complexes

Partyka, David V.; Deligonul, Nihal; Washington, Marlena P.; Gray, Thomas G.

doi:10.1021/om900552e.s001

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fac-Tricarbonyl Rhenium(I) Azadipyrromethene Complexes

journal contribution

posted on 2009-10-26, 00:00 authored by David V. Partyka, Nihal Deligonul, Marlena P. Washington, Thomas G. Gray

Rhenium(I) complexes of azadipyrromethene ligands are reported; three have been characterized crystallographically. The free ligands and their metallo-complexes undergo reductive electrochemistry. Red-light absorption results from optically allowed transitions to a ligand-localized LUMO.