American Chemical Society
om900552e_si_001.pdf (1.27 MB)

fac-Tricarbonyl Rhenium(I) Azadipyrromethene Complexes

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journal contribution
posted on 2009-10-26, 00:00 authored by David V. Partyka, Nihal Deligonul, Marlena P. Washington, Thomas G. Gray
Rhenium(I) complexes of azadipyrromethene ligands are reported; three have been characterized crystallographically. The free ligands and their metallo-complexes undergo reductive electrochemistry. Red-light absorption results from optically allowed transitions to a ligand-localized LUMO.