ol0c00671_si_001.pdf (6.54 MB)
Download fileN‑Nitroheterocycles: Bench-Stable Organic Reagents for Catalytic Ipso-Nitration of Aryl- and Heteroarylboronic Acids
journal contribution
posted on 2020-03-20, 14:33 authored by Kun Zhang, Alena Budinská, Alessandro Passera, Dmitry KatayevPhotocatalytic and metal-free protocols
to access various aromatic
and heteroaromatic nitro compounds through ipso-nitration
of readily available boronic acid derivatives were developed using
non-metal-based, bench-stable, and recyclable nitrating reagents.
These methods are operationally simple, mild, regioselective, and
possess excellent functional group compatibility, delivering desired
products in up to 99% yield.