posted on 2020-03-06, 19:09authored byLiaoyuan Xia, Yu Liao, Yan Qing, Han Xu, Zhifei Gao, Wanqian Li, Yiqiang Wu
Urea
electrolysis is a potential energy-efficient hydrogen (H2) production method that can simultaneously purify urea-rich
wastewater. However, the lack of inexpensive and effective electrocatalysts
for the urea oxidation reaction (UOR) hampers its widespread use.
Herein, hierarchically porous and ultrathin Ni(OH)2 nanostructures in situ grown onto nickel foam (Ni(OH)2@NF) are
developed as efficient and durable electrocatalysts for UOR via a
simple and cost-effective ultrasonic/heating-assisted activation strategy.
The ultrathin Ni(OH)2 nanostructures comprise highly active
surfaces and rapid diffusion pathways for active species; meanwhile,
the excellent electrical conductivity of the NF skeletons effectively
improves the charge transfer of the catalyst. Consequently, this Ni(OH)2@NF electrode exhibits excellent urea catalytic activity (low
oxidation potential of ∼1.35 V at 10 mA cm–2) and has remarkable operational stability (potential increase by
only 0.22% after 40 h of durability testing) that is superior to most
UOR catalysts. By employing the freestanding electrode as the anode
and commercial Pt/C supported on NF as the cathode, this two-electrode
urea electrolysis cell exhibited a current density of 50 mA cm–2 at a low cell voltage (1.45 V, 250 mV below a urea-free
counterpart) with a robust durability (>40 h). This work provides
a valuable insight for designing scalable and high-performance UOR
electrocatalysts, which are promising for utilization in energy-efficient
H2 production.