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In Operando Synchrotron Studies of NH4+ Preintercalated V2O5·nH2O Nanobelts as the Cathode Material for Aqueous Rechargeable Zinc Batteries
journal contribution
posted on 2020-09-03, 09:13 authored by Hainan Zhao, Qiang Fu, Di Yang, Angelina Sarapulova, Qiang Pang, Yuan Meng, Luyao Wei, Helmut Ehrenberg, Yingjin Wei, Chunzhong Wang, Gang ChenNH4+ preintercalated V2O5·nH2O nanobelts with a large interlayer
distance of 10.9 Å were prepared by the hydrothermal method.
The material showed a large specific capacity of 391 mA·h·g–1 at the 500 mA·g–1 current
density in aqueous rechargeable zinc batteries. In operando synchrotron X-ray diffraction demonstrated that the material experienced
reversible solid–solution reaction and two-phase transition
during charge–discharge cycling, accompanied by the reversible
formation/decomposition of a ZnSO4Zn3(OH)6·5H2O byproduct. In operando X-ray absorption spectroscopy confirmed the reversible reduction/oxidation
of V, together with small changes in the VO6 local structure.
The formation of byproduct was attributed to the dehydration of [Zn(H2O)6]2+, which concurrently improved
the desolvation of [Zn(H2O)6]2+ into
Zn2+. Bond valence sum map analysis and electrochemical
impedance spectroscopy demonstrated that the byproduct improved the
charge transfer kinetics of the electrode. Cyclic voltammetry and
galvanostatic intermittent titration technique showed that the electrode
reaction was dominated by ionic intercalation where the discharge
capacity in the voltage window of 1.4–0.85 V was attributed
to the intercalation of [Zn(H2O)6]2+, followed by the intercalation of Zn2+ at 0.85–0.4
V.
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Cyclic voltammetryelectrochemical impedance spectroscopyAqueous Rechargeable Zinc Batteries...operando synchrotron X-ray diffractionZnSO 4 Zn 3electrode reactionOHbyproductbond valence sum map analysiszinc batteriesoperando X-ray absorption spectroscopycharge transfer kinetics10.9 ÅCathode MaterialNH 4hydrothermal methoddischarge capacityOperando Synchrotron StudiesVO 6titration techniquevoltage windowintercalationinterlayer distancetwo-phase transition
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