jo6b01466_si_001.pdf (7.57 MB)
Download file

α‑Regioselective Barbier Reaction of Carbonyl Compounds and Allyl Halides Mediated by Praseodymium

Download (7.57 MB)
journal contribution
posted on 04.08.2016, 00:00 by San Wu, Ying Li, Songlin Zhang
The first utility of praseodymium as a mediating metal in the Barbier reaction of carbonyl compounds with allyl halides was reported in this paper. In contrast to the traditional metal-mediated or catalyzed Barbier reactions, exclusive α-adducts were obtained in this one-pot reaction with a broad scope of substrates and feasible reaction conditions.