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α‑Regioselective Barbier Reaction of Carbonyl Compounds and Allyl Halides Mediated by Praseodymium

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journal contribution
posted on 04.08.2016, 00:00 by San Wu, Ying Li, Songlin Zhang
The first utility of praseodymium as a mediating metal in the Barbier reaction of carbonyl compounds with allyl halides was reported in this paper. In contrast to the traditional metal-mediated or catalyzed Barbier reactions, exclusive α-adducts were obtained in this one-pot reaction with a broad scope of substrates and feasible reaction conditions.

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