American Chemical Society
am402214j_si_001.pdf (1.04 MB)

“Grafting to” as a Novel and Simple Approach for Triple-Shape Memory Polymers

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journal contribution
posted on 2013-08-14, 00:00 authored by Kanitporn Suchao-in, Suwabun Chirachanchai
Maleated-polystyrene-b-poly­(ethylene-co-butylene)-b-polystyrene (m-SEBS) is a block copolymer with two melting temperatures belonging to soft poly­(ethylene-co-butylene) (EB) and hard polystyrene (PS) segments. As EB segments contain anhydride reactive groups, this allows grafting polybutylene succinate (PBS) as another soft segment to m-SEBS backbone to obtain triple-shape memory polymers based on two transition temperatures, i.e., Tm values of EB (at 55–65 °C) and PBS (at 105–115 °C). The present work shows a novel and simple approach of “grafting to” to develop triple-shape memory polymers.