American Chemical Society
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[Cu(L)Mn(N3)2]n:  The First Complex Containing Both Macrocyclic Oxamido and Alternate (μ-1,1 and μ-1,3) Azido Bridges

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journal contribution
posted on 2004-01-10, 00:00 authored by Shi-bin Wang, Guang-ming Yang, Dai-zheng Liao, Li
A wattle-type heteropolynuclear complex [(CuL)Mn(N3)2]n (1) (H2L = 2,3-dioxo-5,6:15,16-dibenzo-1,4,8,13-tetraazacyclo-pentadeca-7,13-diene), which represents the first system with macrocyclic oxamido and alternate azido bridges, forming a one-dimensional chain structure, has been synthesized and characterized by a low temperature magnetic study. The chains are stacked with interchain hydrogen and lead to the structure of a three-dimensional network.