posted on 2024-02-05, 11:43authored byJinsoo Koh, Kang Min Ok
Two novel Cd-based noncentrosymmetric
(NCS) chiral coordination
polymers (CPs), [Cd2((S,S)-IBPhe)2(2,2′-bipy)2]·2H2O [Cd(S)] and [Cd2((R,R)-IBPhe)2(2,2′-bipy)2]·2H2O [Cd(R)] (IBPhe = isophthaloyl-bis-phenylalanine),
have been synthesized through hydrothermal reactions. Cd(S) and Cd(R) crystallize in the monoclinic polar
space group, P21 (No. 4), and exhibit
rigid one-dimensional (1D) chain structures maintained by π–π
interactions between organic ligands, as well as C–H···π
interactions with adjacent chains. The solid-state photoluminescence
data reveal intriguing blue light emission characterized by a phosphorescence
decay time of about 0.41 ms, attributed to ligand-to-ligand charge
transfer effects. Impressively, these Cd-based compounds exhibit a
high degree of stability across various solvents and pH conditions.
Furthermore, their exceptional adsorption capacities for Congo red
are evidenced by maximum adsorption efficiencies of 850.82 mg/g for
Cd(S) and 817.71 mg/g for Cd(R).
These findings underline the potential of these NCS chiral coordination
polymers for diverse applications ranging from efficient dye removal
to enhanced photoluminescence.