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(4,4)-Connected Self-penetrating Pillared-Layered Metal–Organic Framework Based on a Nanosized Flexible Aromatic Carboxylic Acid Ligand

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journal contribution
posted on 05.09.2012, 00:00 by Li-Hui Cao, Hai-Yang Li, Shuang-Quan Zang, Hong-Wei Hou, Thomas C. W. Mak
A novel coordination polymer based on a nanosized flexible aromatic carboxylic acid ligand has been successfully synthesized by solvothermal reaction, [Cd­(obda)0.5(bpy)­(H2O)]·2H2O (1) (H4obda = 1,4-bis­(4-oxy-1,2-benzenedicarboxylic acid)­benzene, bpy = 4,4′- bipyridine), exhibiting a (4,4)-connected self-penetrating pillared-layered metal–organic framework. In addition, photoluminescence was also performed on 1.

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