Volumetric
Properties of Binary Mixtures of 1‑Butyl-3-Methylimidazolium
Tris(pentafluoroethyl)trifluorophosphate with N‑Methylformamide, N‑Ethylformamide, N,N‑Dimethylformamide, N,N‑Dibutylformamide,
and N,N‑Dimethylacetamide
from (293.15 to 323.15) K
posted on 2014-11-13, 00:00authored byMilan Vraneš, Aleksandar Tot, Nebojša Zec, Snežana Papović, Slobodan Gadžurić
Volumetric properties of 1-butyl-3-methylimidazolium
tris(pentafluoroethyl)trifluorophosphate
([BMIM][FAP]) ionic liquid binary mixtures with two protic amides: N-methyl-formamide (NMF) and N-ethylformamide
(NEF), and three aprotic amides: N,N-dimethylformamide (DMF), N,N-dibutylformamide
(DBF), and N,N-dimethylacetamide
(DMA), are calculated from the experimental densities and reported
in the temperature range from (293.15 to 323.15) K and at atmospheric
pressure (0.1 MPa) over the whole composition range. The excess molar
volumes have positive values in the whole concentration range, with
maximum values in the range between 0.3 and 0.6 ionic liquid mole
fraction. Higher values of excess molar volumes are observed in the
mixtures containing aprotic amides (DMF, DBF, DMA). Also, the molar
volume of binary mixtures, the apparent molar volumes, the partial
molar volumes of the components, and the partial molar volumes of
the components at infinite dilution are calculated. All of the results
are compared with those obtained for pyrrolidinium-based ionic liquids
with the same anion in the mixtures with the selected amides.