Visible-Light-Induced Radical gem-Iodoallylation of 2,2,2-Trifluorodiazoethane

A visible-light-induced radical gem-iodoallylation of CF₃CHN₂ was developed under mild conditions, delivering a variety of α-CF₃-substituted homoallylic iodide compounds in moderate to excellent yields. The transformation features broad substrate scope, good functional group compatibility, and operational simplicity. The described protocol provides a convenient and attractive tool to apply CF₃CHN₂ as CF₃-introduction reagent in radical synthetic chemistry.