American Chemical Society
gg1c00007_si_001.pdf (3.76 MB)

Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System

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journal contribution
posted on 2021-06-22, 11:33 authored by Tatsuhiro Uchikura, Yurina Hara, Kazushi Tsubono, Takahiko Akiyama
Developed herein is a visible-light-driven synthesis of sulfides by an electron donor–acceptor/single electron transfer and hydrogen atom transfer combined system without transition metals and strong oxidants. This reaction proceeds through the excitation of an electron donor–acceptor complex between a thiolate and an aryl halide, followed by the hydrogen atom transfer from an alkane to the generated aryl radical.