gg1c00007_si_001.pdf (3.76 MB)
Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System
journal contribution
posted on 2021-06-22, 11:33 authored by Tatsuhiro Uchikura, Yurina Hara, Kazushi Tsubono, Takahiko AkiyamaDeveloped herein is a visible-light-driven
synthesis of sulfides by an electron donor–acceptor/single
electron transfer and hydrogen atom transfer combined system without
transition metals and strong oxidants. This reaction proceeds through
the excitation of an electron donor–acceptor complex between
a thiolate and an aryl halide, followed by the hydrogen atom transfer
from an alkane to the generated aryl radical.