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Vinyl Diazophosphonates as Precursors to Quaternary Substituted Indolines and Cyclopentenes

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journal contribution
posted on 18.02.2011, 00:00 by Jin Wang, Vyacheslav Boyarskikh, Jon D. Rainier
Vinyl diazophosphonates can be stereoselectively synthesized and, depending upon their substitution pattern, undergo intramolecular C−H insertion reactions or sulfonium ylide rearrangements when exposed to Rh2(OAc)4.