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Vapor Phase near Infrared Spectroscopy of the Hydrogen Bonded Methanol−Trimethylamine Complex

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journal contribution
posted on 10.08.2006, 00:00 by Daryl L. Howard, Henrik G. Kjaergaard
The spectroscopy of the vapor phase hydrogen bonded complex formed between methanol and trimethylamine has been studied in the near-infrared region. A combination band involving one quantum of OH stretch and one quantum of COH bend has been observed for the complex. The much less intense first OH-stretching overtone transition has been tentatively assigned. This assignment is supported by anharmonic oscillator local mode calculations.