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Vapor–Liquid Equilibrium Data for the Morpholine-4-carbaldehyde + n‑Hexane or n‑Heptane Binary Systems Using a Static-Synthetic Apparatus

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posted on 2013-09-12, 00:00 authored by Kuveneshan Moodley, Paramespri Naidoo, Johan David Raal, Deresh Ramjugernath
Precise isothermal binary vapor–liquid equilibrium (VLE) measurements were performed for the morpholine-4-carbaldehyde + n-hexane or n-heptane systems at (343.15, 363.15, and 393.15) K using a static-synthetic apparatus. The Px data measured were processed using both the model-dependent and model-independent approaches. Infinite dilution activity coefficients were estimated by the extrapolation of VLE data by three different methods. Excess enthalpy and entropy data were predicted from VLE data using the Gibbs–Helmholtz relation.

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