posted on 2013-09-12, 00:00authored byKuveneshan Moodley, Paramespri Naidoo, Johan David Raal, Deresh Ramjugernath
Precise
isothermal binary vapor–liquid equilibrium (VLE)
measurements were performed for the morpholine-4-carbaldehyde + n-hexane or n-heptane systems at (343.15,
363.15, and 393.15) K using a static-synthetic apparatus. The P–x data measured were processed
using both the model-dependent and model-independent approaches. Infinite
dilution activity coefficients were estimated by the extrapolation
of VLE data by three different methods. Excess enthalpy and entropy
data were predicted from VLE data using the Gibbs–Helmholtz
relation.