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Use of in Situ Isopropoxide Protection in the Metal−Halogen Exchange of Arylboronates

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journal contribution
posted on 17.08.2007, 00:00 by Qin Jiang, Meagan Ryan, Paul Zhichkin
Isopropoxide protection of arylboronates allowed their use in metal−halogen exchange reactions. The isopropoxide-protected borate species were obtained from a boronate or in situ from dibromoarenes. meta- and para-dibromoarenes were converted via these intermediates into functionalized arylboronates in a one-pot manner.