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Unique Two-Dimensional Indium Telluride Templated by a Rare Wheel-Shaped Heterobimetallic Mn/In Cluster

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journal contribution
posted on 17.04.2020, 13:40 by Yao Fu, Jian Zhou, Hua-Hong Zou, Filipe A. Almeida Paz, Xing Liu, Lianshe Fu
A new indium telluride, [Mn4.78In2.22(ea)12]n[In9.79Mn0.21Te17]n (where Hea = ethanolamine), containing unprecedented nonsupertetrahedral [In9.79Mn0.21Te21] units is the first example of a two-dimensional indium telluride framework templated by a rare high-nuclearity wheel-shaped heterometallic [Mn4.78In2.22(ea)12]4.22+ cluster. The photocurrent response and magnetic properties were investigated.