Unique Two-Dimensional Indium Telluride Templated by a Rare Wheel-Shaped Heterobimetallic Mn/In Cluster

A new indium telluride, [Mn_4.78In_2.22(ea)₁₂]_n[In_9.79Mn_0.21Te₁₇]_n (where Hea = ethanolamine), containing unprecedented nonsupertetrahedral [In_9.79Mn_0.21Te₂₁] units is the first example of a two-dimensional indium telluride framework templated by a rare high-nuclearity wheel-shaped heterometallic [Mn_4.78In_2.22(ea)₁₂]^4.22+ cluster. The photocurrent response and magnetic properties were investigated.