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Unexpected Phenyl Group Rearrangement during an Intramolecular Scholl Reaction Leading to an Alkoxy-Substituted Hexa-peri-hexabenzocoronene

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journal contribution
posted on 21.06.2007, 00:00 by Xi Dou, Xiaoyin Yang, Graham J. Bodwell, Manfred Wagner, Volker Enkelmann, Klaus Müllen
A simple dimethoxy-substituted hexa-peri-hexabenzocoronene (m-dimethoxy HBC) was unexpectedly obtained along with a bis-spirocyclic dienone during an intramolecular Scholl reaction of its para isomer.