jo9b02091_si_002.pdf (1.69 MB)
Unexpected Formation of Hexasubstituted Arenes through a 2‑fold Palladium-Mediated Ligand Arylation
journal contribution
posted on 2019-09-24, 20:45 authored by Corin
C. Wagen, Bryan T. Ingoglia, Stephen L. BuchwaldA rearrangement
reaction of biarylphosphine-supported Pd(II) complexes
was employed to synthesize 1,3,5-triaryl 2,4,6-triisopropylbenzene
compounds, a class of molecules that has not previously been reported.
The strain of the central hexasubstituted ring was investigated via
X-ray crystallography.