posted on 2018-05-18, 00:00authored byHongbao Yao, Yujun Wang, Yu Jing, Guangsheng Luo
Ceria nanorods enclosed with {110}/{100}
planes and ceria nanocubes
with {100} planes have been successfully prepared using a homemade
microfluidic system in a continuous, ultrafast and shape-controllable
manner. Only 8 min of reaction time are needed rather than days to
synthesize ceria nanostructures in the traditional batch hydrothermal
method. During the synthesis, reaction temperatures and base concentration
have been demonstrated as the key factors responsible for the shape
evolution. Accordingly, a morphological phase diagram was determined.
In addition, polyvinylpyrrolidone was introduced to realize the transformation
from ceria nanorods to nanocubes under unfavorable hydrothermal conditions.
Catalytic performance of different CeO2 architectures was
also examined in decomposing hydrogen peroxide and a reactivity trend
(nanoparticles < nanorods < nonocubes) was observed. This is
assumed to be related with different surface oxygen vacancy amounts
as a result of {110}/{100} preferential planes, as confirmed by X-ray
photoelectron spectroscopy and Raman analyses as well as density functional
theory (DFT+U) calculations.