posted on 2019-09-24, 18:35authored byAsier Fdz De Anastro, Luca Porcarelli, Matthias Hilder, Carlos Berlanga, Montse Galceran, Patrick Howlett, Maria Forsyth, David Mecerreyes
A simple
method to prepare a mechanically robust ionogel film by
fast (<1 min) UV photopolymerization of poly(ethylene glycol) diacrylate
in the presence of an ionic liquid electrolyte based on N-propyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide
and sodium bis(fluorosulfonyl)imide is demonstrated. The ionogels
showed very high ionic conductivity at 50 °C (6.5 × 10–3 S·cm–1) close to the liquid
counterpart (7.8 × 10–3 S·cm–1). High salt concentration in the ionogels was beneficial for the
sodium plating and stripping. Na/ionogel/NaFePO4 full cells
delivered a high specific capacity of 152 mAh g–1 at 50 °C with good capacity retention.