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Two Chain Compounds of [M(N3)2(HCOO)][(CH3)2NH2] (M = Fe and Co) with a Mixed Azido/Formato Bridge Displaying Metamagnetic Behavior

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journal contribution
posted on 03.04.2006, 00:00 by Tao Liu, Yanjuan Zhang, Zheming Wang, Song Gao
Two new magnetic chain compounds, where the anionic [M(N3)2(HCOO)-]n chains with a 3-fold bridge of two end-on azido and one synsyn formato ligands are isolated by the cations of [(CH3)2NH2]+, exhibit metamagnetism because of the strong intrachain ferromagnetic coupling versus the weak interchain antiferromagnetic coupling.