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Two-Dimensional Luminescent Rectangular Molecular Grids Containing Copper(I)−Olefin Bonds as Bridging Spacers

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journal contribution
posted on 07.12.2001, 00:00 authored by Jing Zhang, Ren-Gen Xiong, Xue-Tai Chen, Ziling Xue, Shie-Ming Peng, Xiao-Zeng You
The reaction of CuCl with 4-vinylpyridine (4-VPY) under hydrothermal conditions affords a 2-D copper(I)−olefin luminescent coordination polymer, [Cu(4-VPYA)Cl]n (1), with an approximately molecular rectangular grid dimension of 10.576 × 7.322 Å.