Trion-Induced Distinct Transient Behavior and Stokes Shift in WS₂ Monolayers

Understanding the excitonic behavior in two-dimensional transition-metal dichalcogenides (2D TMDs) is of both fundamental interest and critical importance for optoelectronic applications. Here, we investigate the transient excitonic behavior and Stokes shift in WS₂ monolayers on both sapphire and glass substrates. Trion formation was confirmed as the origin of the distinct photoluminescence (PL) emission and Stokes shift in WS₂ monolayers. Moreover, the transient studies demonstrate faster recombination of both the exciton and the short-lived trion on the glass substrate as compared to that on the sapphire substrate, owing to the heavier n-doping and greater number of defects introduced by the glass substrate. In addition, a long-lived trion species attributed to the intervalley triplet trion was observed on the glass substrate, with a lifetime on the nanosecond time scale. These findings offer a comprehensive understanding of the excitonic behavior and Stokes shift in WS₂ monolayers and will lay the foundation for further fundamental investigations in the field.