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Trigermaallene and 1,3-Digermasilaallene

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journal contribution
posted on 17.01.2005, 00:00 by Takeaki Iwamoto, Hidenori Masuda, Chizuko Kabuto, Mitsuo Kira
X-ray analysis of the first trigermaallene (3) and 1,3-digermasilaallene (4) revealed that the trimetallaallene skeletons are not linear but significantly bent, similarly to the corresponding trisilaallene 2. In contrast to 2, no dynamic disorder was observed for 3 and 4.