Trigermaallene and 1,3-Digermasilaallene

Iwamoto, Takeaki; Masuda, Hidenori; Kabuto, Chizuko; Kira, Mitsuo

doi:10.1021/om049183e.s003

Trigermaallene and 1,3-Digermasilaallene

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posted on 2005-01-17, 00:00 authored by Takeaki Iwamoto, Hidenori Masuda, Chizuko Kabuto, Mitsuo Kira

X-ray analysis of the first trigermaallene (3) and 1,3-digermasilaallene (4) revealed that the trimetallaallene skeletons are not linear but significantly bent, similarly to the corresponding trisilaallene 2. In contrast to 2, no dynamic disorder was observed for 3 and 4.

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trisilaallene 2 Digermasilaallene analysis trigermaallene contrast Trigermaallene trimetallaallene skeletons disorder digermasilaallene

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Trigermaallene and 1,3-Digermasilaallene

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