American Chemical Society
ol2001182_si_001.pdf (8.34 MB)

Transfer of Chirality by the Use of an All Carbon Tether

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journal contribution
posted on 2011-03-04, 00:00 authored by Marie-Gabrielle Braun, Rama Heng, Samir Z. Zard
Methylketone side chains can be used to direct the creation of one or more chiral centers, including quaternary centers, by exploiting the ability of the radical xanthate transfer process to mediate six-membered ring formation.