nl6b02164_si_001.pdf (2.06 MB)
Tracking Optical Welding through Groove Modes in Plasmonic Nanocavities
journal contributionposted on 2016-08-16, 00:00 authored by J. Mertens, A. Demetriadou, R. W. Bowman, F. Benz, M.-E. Kleemann, C. Tserkezis, Y. Shi, H. Y. Yang, O. Hess, J. Aizpurua, J. J. Baumberg
We report the light-induced formation of conductive links across nanometer-wide insulating gaps. These are realized by incorporating spacers of molecules or 2D monolayers inside a gold plasmonic nanoparticle-on-mirror (NPoM) geometry. Laser irradiation of individual NPoMs controllably reshapes and tunes the plasmonic system, in some cases forming conductive bridges between particle and substrate, which shorts the nanometer-wide plasmonic gaps geometrically and electronically. Dark-field spectroscopy monitors the bridge formation in situ, revealing strong plasmonic mode mixing dominated by clear anticrossings. Finite difference time domain simulations confirm this spectral evolution, which gives insights into the metal filament formation. A simple analytic cavity model describes the observed plasmonic mode hybridization between tightly confined plasmonic cavity modes and a radiative antenna mode sustained in the NPoM. Our results show how optics can reveal the properties of electrical transport across well-defined metallic nanogaps to study and develop technologies such as resistive memory devices (memristors).
light-induced formationresults showDark-field spectroscopy monitorslaser irradiationplasmonic systemplasmonic modeGroove ModesPlasmonic Nanocavitiescavity modelconductive linksgold plasmonic nanoparticle-on-mirrorbridge formationplasmonic cavity modesNPoMs controllably2 D monolayersTracking Optical Weldingplasmonic mode hybridizationFinite difference time domain simulationsnanometer-wide plasmonic gapsconductive bridgesradiative antenna modemetal filament formationmemory devices