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Total Synthesis of (+)-Superstolide A

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journal contribution
posted on 05.03.2008, 00:00 by Mariola Tortosa, Neal A. Yakelis, William R. Roush
A convergent and highly stereocontrolled synthesis of (+)-superstolide A (1) has been accomplished. Key steps of this synthesis include the intramolecular Suzuki reaction of 26 and the highly diastereoselective transannular Diels−Alder cyclization of macrocyclic octaene 3.