Titanocene(III) Chloride-Mediated Reductions of Oxazines, Hydroxamic Acids, and N-Hydroxy Carbamates

Cesario, Cara; Tardibono, Lawrence P.; Miller, Marvin J.

doi:10.1021/jo802184y.s001

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Titanocene(III) Chloride-Mediated Reductions of Oxazines, Hydroxamic Acids, and N-Hydroxy Carbamates

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posted on 02.01.2009, 00:00 by Cara Cesario, Lawrence P. Tardibono, Marvin J. Miller

Titanocene(III) chloride (Cp₂TiCl), generated in situ, reduces N−O bonds of various substrates in good to excellent yields (72−95%). Reactions may be performed with stoichiometric Cp₂TiCl or with catalytic Cp₂TiCl.

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Titanocene(III) Chloride-Mediated Reductions of Oxazines, Hydroxamic Acids, and N-Hydroxy Carbamates

The Journal of Organic Chemistry

Keywords

Titanocene Cp 2TiCl stoichiometric Cp 2TiCl Hydroxamic Acids

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Titanocene(III) Chloride-Mediated Reductions of Oxazines, Hydroxamic Acids, and N-Hydroxy Carbamates

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