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Titanocene(III) Chloride-Mediated Reductions of Oxazines, Hydroxamic Acids, and N-Hydroxy Carbamates

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journal contribution
posted on 02.01.2009, 00:00 by Cara Cesario, Lawrence P. Tardibono, Marvin J. Miller
Titanocene(III) chloride (Cp2TiCl), generated in situ, reduces N−O bonds of various substrates in good to excellent yields (72−95%). Reactions may be performed with stoichiometric Cp2TiCl or with catalytic Cp2TiCl.