posted on 2012-11-08, 00:00authored byHugo F.
D. Almeida, Helena Passos, José A. Lopes-da-Silva, Ana M. Fernandes, Mara G. Freire, João A. P. Coutinho
Ionic liquids (ILs) with improved hydrogen-bonding acceptor
abilities,
such as acetate-based compounds, have shown great potential for CO2 capture and biomass dissolution. In this context, the knowledge
of the thermophysical properties of acetate-based fluids is essential
for the design and scale-up of related processes. However, at this
stage, acetate-based ILs are still poorly characterized. In this work,
four thermophysical properties, specifically, density, viscosity,
refractive index, and surface tension, were determined for five acetate-based
ILs. Both protic and aprotic ILs were investigated, namely, N,N-dimethyl-N-ethylammonium
acetate, 1-ethylimidazolium acetate, 1-ethyl-3-methylimidazolium acetate,
1-butyl-3-methylimidazolium acetate, and 1-butyl-1-methylpyrrolidinium
acetate. From the temperature dependence of the measured properties,
additional properties, such as the isobaric thermal expansion coefficient,
the surface entropy and enthalpy, and the critical temperature, were
further estimated.