posted on 2020-03-16, 22:43authored byHong Li, Jian Na, Haifeng Cong, Liangquan Wu, Lei Zhao, Xingang Li, Xin Gao
Ethanol carbonylation catalyzed with
iodoethane has gradually received
much attention as a promising propionic acid production process. However,
the separation of products is one of the most key bottle-neck problems
for this method used in the industry because of the existence of the
azeotrope and the lack of thermodynamic data for designing the product
separation process. In this article, the vapor–liquid equilibrium
data of iodoethane/propionic acid and iodoethane/ethyl propionate
were measured and regressed. Based on the thermodynamics data, two
heterogeneous azeotrope distillation separation processes with different
reflux strategies to recover the propionic acid were simulated and
compared, which was optimized by minimizing the total annual cost
and maximizing the recovery of propionic acid. The result indicates
that the azeotrope distillation process with the two phases refluxing
was proved to be a better strategy currently to recover more propionic
acid. These results also provide chemical engineers with an alternative
way to produce propionic acid.