It is significant and valuable to investigate novel and
high-performance
red-emitting phosphors for high-quality wLED applications. Based on
this consideration, we developed a novel Mn2+-doped red
Ca18K3Sc(PO4)14:Mn2+ (CKSP:Mn2+) phosphor. The emission peak of CKSP:Mn2+ is located at 640 nm, presenting a broadband red emission
with a fwhm of 79 nm under 405 nm excitation. The CKSP:1.0Mn2+ phosphor shows superior thermal stability. At 150 °C, the integrated
PL intensity and peak intensity of the CKSP:1.0Mn2+ phosphor
maintain 93.2 and 85.7% of those at 25 °C, respectively. Through
the strategy of energy transfer among Ce3+-Eu2+-Mn2+, the PL intensity of Mn2+ has increased
by nearly 118 times, and the quantum yield has improved from 6 up
to 72%. The structure-related photoluminescence and energy transfer
mechanisms are discussed in detail. The as-fabricated wLED pumped
by a 370 nm LED chip combining commercial the green (Sr,Ba)2SiO4:Eu2+ phosphor, blue BaMgAl10O17:Eu2+ phosphor, and the as-synthesized CKSP:1.0Mn2+, 0.02Eu2+, 0.40Ce3+ phosphor shows
excellent color quality (CCT = 5555 K, Ra = 87), which indicates that
the CKSP:1.0Mn2+, 0.02Eu2+, 0.40Ce3+ phosphor has extraordinary broad prospects in future wLED applications.