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The Trichloromethide and Bromodichloromethide Carbanions

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journal contribution
posted on 17.12.2009, 00:00 by Robert A. Moss, Min Zhang, Karsten Krogh-Jespersen
Reactions of photochemically generated dichlorocarbene with chloride or bromide ions afford trichloromethide or bromodichloromethide carbanions, the central intermediates in the classical base-catalyzed generation of dichlorocarbene from haloforms.