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The Cation as a Tool to Get Spin-Canted Three-Dimensional Iron(III) Networks

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journal contribution
posted on 23.08.2004, 00:00 by Donatella Armentano, Giovanni De Munno, Teresa F. Mastropietro, Davide M. Proserpio, Miguel Julve, Francesc Lloret
Alkyl-substituted ammonium cations (X) allow the preparation of a series of spin-canted oxo- and oxalato-bridged three-dimensional iron(III) networks, exhibiting magnetic ordering at Tc values ranging from 40 to 56 K. The value of Tc varies with the cation despite the lack of significant structural modifications.