Terpene Based Sustainable Elastomer for Low Rolling
Resistance and Improved Wet Grip Application: Synthesis, Characterization
and Properties of Poly(styrene-co-myrcene)
posted on 2016-08-17, 00:00authored byPreetom Sarkar, Anil K. Bhowmick
Incited by the unprecedented
surge of developing sustainable polymers,
we demonstrate herein a green emulsion polymerization route toward
the development of sustainable rubbery materials based on β-myrcene
(MY) and styrene (ST) for low rolling resistance and improved wet
grip applications. The microstructure of the synthesized copolymers
was found to be governed by the ST weight percent. For example, the
copolymers having less than 40 wt % of ST had 1,2 vinyl and 3,4 addition products along with 1,4-cis and
-trans microstructure of the polymyrcene unit, whereas
the copolymers having higher weight percent of ST had only 1,4-cis and -trans microstructure of the polymyrcene
unit. The copolymers displayed improved onset degradation temperature
and subambient glass transition temperatures. The copolymer having
a 70/30 weight/weight ratio of MY/ST displayed a molecular weight
of 51 500 Da and a glass transition temperature of −35.2
°C. The 70/30 rubber vulcanizate exhibited satisfactory mechanical
properties (tensile strength of 6.4 MPa and elongation at break of
395%). Dynamic mechanical analysis of the vulcanizate reveals improved
traction and low rolling loss over a standard tire tread compound,
thereby making it a promising material for tires.