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Terminal Titanium(IV) (Trimethylsilyl)imides Prepared by Oxidatively Induced Trimethylsilyl Abstraction

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journal contribution
posted on 22.05.2006, 00:00 by Brad C. Bailey, Falguni Basuli, John C. Huffman, Daniel J. Mindiola
Titanium (trimethylsilyl)imide triflate complexes of the type (L)TiNSiMe3(OTf) (L- = [ArNC(CH3)]2CH, Ar = 2,6-iPr2C6H3; L- = N[2-P(CHMe2)2-4-MeC6H3]2) can be readily prepared by one-electron oxidation and subsequent trimethylsilyl abstraction in the Ti(III) precursors (L)TiCl(N{SiMe3}2).