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TEMPO-catalyzed Aerobic Oxygenation and Nitrogenation of Olefins via CC Double-Bond Cleavage

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journal contribution
posted on 14.08.2013, 00:00 by Teng Wang, Ning Jiao
A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via CC double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.