ol801452c_si_001.pdf (47.46 MB)

TBOxCrIIICl-Catalyzed Enantioselective Synthesis of 1,3-Butadien-2-ylcarbinols

Download (47.46 MB)
journal contribution
posted on 18.09.2008, 00:00 by Marina Naodovic, Guoyao Xia, Hisashi Yamamoto
A highly enantioselective synthesis of 1,3-butadien-2-ylcarbinols is achieved by using the TBOxCrIIICl catalyst and homoallenylbromide 1. This method can be further extended to the enantio- and regioselective propargylation of aldehydes.