ol3034093_si_001.pdf (1.92 MB)
Synthesis of the Putative Structure of (±)-Amarbellisine
journal contributionposted on 2013-01-18, 00:00 authored by Dandan Liu, Jingbo Chen, Long Ai, Hongbin Zhang, Jianping Liu
The title compound was synthesized mainly by palladium catalytic coupling, cyclopropyl ring-opening rearrangement, epoxidation, Swern oxidation, demethanol reactions, and selective reduction. This synthesis was achieved in 16 steps with 9.7% overall yield. Unfortunately, the published spectroscopic data do not match with those of our synthetic compound.