ol100515m_si_002.pdf (11.44 MB)
Synthesis of the C9−C23 (C9′−C23′) Fragment of the Dimeric Natural Product Rhizopodin
journal contributionposted on 2010-05-07, 00:00 authored by Zheng Chen, Liankai Song, Zhengshuang Xu, Tao Ye
A stereoselective assembly of the C9−C23 (C9′−C23′) fragment of rhizopodin, a 38-membered bis-lactone natural product, has been developed. A highly efficient approach to this fragment assembles >50% of the carbon skeleton and the stereochemical elements present in the natural product.