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Synthesis of an Azaphosphatriptycene and Its Rhodium Carbonyl Complex

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journal contribution
posted on 23.04.2019, 19:14 by Yu Cao, Jonathan W. Napoline, John Bacsa, Pamela Pollet, Jake D. Soper, Joseph P. Sadighi
A 10-aza-9-phosphatriptycene is accessible on a gram scale, in three laboratory steps from commercially available precursors. Infrared spectroscopy of a rhodium­(I) carbonyl complex bearing this ligand reflects the weak σ-donor/strong π-acceptor character of the phosphine; the solid-state structure reveals moderate steric demand. This ligand supports highly active catalysts for the hydroformylation of cyclic alkenes.

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