posted on 2024-03-07, 21:29authored byNoa Afik, Sandhiya Murugesan, Karam Shreteh, Helena Fridman, Yara Hijaze, Michael Volokh, Taleb Mokari
Doped and alloyed transition metal-oxides (TMOs) attract
vast attention
owing to their tunable electronic properties (e.g., conductivity,
band gap, and optical absorption), making them appealing for many
(photo)electronic, chromic, and green energy applications. Dual-functional
materials combining electrochromic (EC) and energy storage (e.g.,
supercapacitor, SC) applications are of interest as they can store
energy while shading the light transmission through a window or give
off a visual signal of their current energy storage state by a color
change. Pure tungsten-oxides exhibit distinctive EC properties but
attain low energy density compared to other TMOs (e.g., MoO3 and V2O5). The coloration efficiency and energy
density can be enhanced by controlling the morphology, size, and composition
of the nanoscale TMOs that constitute the active EC film. Thus far,
most EC-SC works showed a trade-off between increased areal capacitance
and a decrease in the coloration efficiency or transmittance; the
improved EC-SC properties for doped or alloyed metal-oxides were related
mostly to the small grain size or to structural distortion caused
by the added cation, exhibiting more active sites. Herein, we demonstrate
a straightforward and facile synthesis of crystalline Mo/V-alloyed
tungsten-oxide ultrathin nanowires (uNWs). We investigated the growth
mechanism and succeeded in preserving the crystallinity up to 25%
(atomic) alloying. The additional properties (compared to unmodified
tungsten-oxide) of the alloyed uNWs, such as absorbance peaks, lead
to improved specific capacitance while preserving the high coloration
efficiency of uNW W–O, and in the case of W–Mo–O,
a better coloration efficiency is measured.