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Synthesis of Substituted 3(2H)‑Furanones Using Alkylative Intramolecular Cyclization of Sulfonium Salts

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journal contribution
posted on 29.08.2016, 13:45 by Sho Inagaki, Mika Ukaku, Akira Chiba, Fumi Takahashi, Yasuharu Yoshimi, Toshio Morita, Tomikazu Kawano
The facile alkylative intra­molecular cyclization of 3-alkoxy­carbonyl-2-oxo­propyl­diphenyl­sulfonium salts is described. This simple method can be readily applied to the synthesis of a novel family of 4-alkylated 3­(2H)-furanones in moderate to high yields under mild conditions via a one-pot process.

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