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Synthesis of Phosphoramidates: A Facile Approach Based on the C–N Bond Formation via Ir-Catalyzed Direct C–H Amidation

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journal contribution
posted on 17.10.2014, 00:00 by Hyunwoo Kim, Juhyeon Park, Jeung Gon Kim, Sukbok Chang
A new synthetic route to phosphoramidates by intermolecular C–H amidation is presented. Substrates with assorted directing groups were activated by an iridium-based catalyst system and reacted with a number of phosphoryl azides, executing efficient phosphoramidate synthesis via C–N bond formations.

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