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Synthesis of N-Confused Tetraphenylporphyrin Rhodium Complexes Having Versatile Metal Oxidation States

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journal contribution
posted on 01.12.2008, 00:00 by Alagar Srinivasan, Motoki Toganoh, Teppei Niino, Atsuhiro Osuka, Hiroyuki Furuta
A variety of N-confused tetraphenylporphyrin rhodium complexes were synthesized, and their structures and physical properties were investigated. Depending on the reaction conditions, the rhodium(I), -(III), and -(IV) complexes were produced, which exemplified the versatile coordination mode of N-confused porphyrin ligands.