ic5b01922_si_001.pdf (398.37 kB)
Download fileSynthesis of Inert Homo- and Heterodinuclear Rare-Earth Cryptates
journal contribution
posted on 2015-10-19, 00:00 authored by Jessica Wahsner, Michael SeitzA new ditopic cryptand based on two
tris(biaryl)-based binding pockets bridged by a 2,2′-bipyrimidine
unit enables the selective synthesis of homo- and heterodinuclear
rare-earth cryptates, which are kinetically inert under challenging
conditions and can even be purified by preparative high-performance
liquid chromatography.