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Synthesis of Fullerooxazoles: Novel Reactions of [60]Fullerene with Nitriles Promoted by Ferric Perchlorate

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journal contribution
posted on 15.08.2008, 00:00 by Fa-Bao Li, Tong-Xin Liu, Guan-Wu Wang
The ferric perchlorate-mediated reactions of C60 with various nitriles in o-dichlorobenzene under nitrogen atmosphere afforded the rare fullerooxazoles, which would be difficult to prepare by other methods. A possible reaction mechanism for the formation of the fullerooxazoles was proposed.